BROWSE

Related Scientist

Researcher

분자활성 촉매반응 연구단
분자활성 촉매반응 연구단
more info

Synthetic uses of ammonia in transition-metal catalysis

Cited 41 time in webofscience Cited 0 time in scopus
433 Viewed 20 Downloaded
Title
Synthetic uses of ammonia in transition-metal catalysis
Author(s)
Jinho Kim; Hyun Jin Kim; Sukbok Chang
Publication Date
2013-06
Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v., no.16, pp.3201 - 3213
Publisher
WILEY-V C H VERLAG GMBH
Abstract
Ammonia (NH3) is a cheap, abundant, and readily available nitrogen source, being one of the chemicals produced in the greatest quantities. Whereas ammonia is utilized mainly as a feedstock for the production of fertilizers, it is also employed in industry as a component of various nitrogen-containing compounds. In metal catalysis, in contrast, ammonia has been used only with limited success, due to several difficulties such as generation of stable Lewis acid-base adducts, facile ligand exchange for ammonia in active metal complexes, a propensity towards undesired second transformations of initially formed species, and the requirement for special equipment to run the reactions. Despite these obstacles, the direct use of ammonia in catalysis has continuously attracted great interest, leading recently to significant progress. Whereas liquid or gaseous ammonia were most commonly employed in the past, under harsh conditions, notable catalytic reactions using easy-to-handle ammonium salts under milder and more convenient conditions have now been developed. In this review we briefly describe the most recent examples of transition-metal-catalyzed reactions using ammonia or ammonium salts. Although ammonia (NH3) is a cheap, abundant, and readily available nitrogen source, it has rarely been used in transition-metal catalysis, due to several obstacles. However, significant advances in the metal-mediated utilization of ammonia have been made recently. This review presents the most recent examples in metal-mediated amination and other relevant reactions with ammonia or ammonium salts. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
URI
https://pr.ibs.re.kr/handle/8788114/1315
ISSN
1434-193X
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
Files in This Item:
2013-06-European Journal of Organic Chemistry-Synthetic Uses.pdfDownload

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse