BROWSE

Related Scientist

cristobal,quintana's photo.

cristobal,quintana
인공지능및로봇기반합성연구단
more info

ITEM VIEW & DOWNLOAD

Proving Cooperativity of a Catalytic Reaction by Means of Nanoscale Geometry: The Case of Click Reaction

DC Field Value Language
dc.contributor.authorCristóbal Quintana-
dc.contributor.authorJuan C. Ahumada-
dc.contributor.authorGuillermo Ahumada-
dc.contributor.authorYaroslav Sobolev-
dc.contributor.authorMinju Kim-
dc.contributor.authorAtabay Allamyradov-
dc.contributor.authorBartosz A. Grzybowski-
dc.date.accessioned2023-01-27T01:55:27Z-
dc.date.available2023-01-27T01:55:27Z-
dc.date.created2022-07-11-
dc.date.issued2022-06-
dc.identifier.issn0002-7863-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/12917-
dc.description.abstractEstablishing whether a reaction is catalyzed by a single-metal catalytic center or cooperatively by a fleeting complex encompassing two such centers may be an arduous pursuit requiring detailed kinetic, isotopic, and other types of studies─as illustrated, for instance, by over a decade-long work on single-copper versus di-copper mechanisms of the popular click reaction. This paper describes a method to interrogate such cooperative mechanisms by a nanoparticle-based platform in which the probabilities of catalytic units being proximal can be varied systematically and, more importantly, independently of their volume concentration. The method relies on geometrical considerations rather than a detailed knowledge of kinetic equations, yet the scaling trends it yield can distinguish between cooperative and non-cooperative mechanisms.-
dc.language영어-
dc.publisherNLM (Medline)-
dc.titleProving Cooperativity of a Catalytic Reaction by Means of Nanoscale Geometry: The Case of Click Reaction-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000819337500001-
dc.identifier.scopusid2-s2.0-85133143944-
dc.identifier.rimsid78457-
dc.contributor.affiliatedAuthorCristóbal Quintana-
dc.contributor.affiliatedAuthorJuan C. Ahumada-
dc.contributor.affiliatedAuthorGuillermo Ahumada-
dc.contributor.affiliatedAuthorYaroslav Sobolev-
dc.contributor.affiliatedAuthorMinju Kim-
dc.contributor.affiliatedAuthorAtabay Allamyradov-
dc.contributor.affiliatedAuthorBartosz A. Grzybowski-
dc.identifier.doi10.1021/jacs.2c02556-
dc.identifier.bibliographicCitationJournal of the American Chemical Society, v.144, no.25, pp.11238 - 11245-
dc.relation.isPartOfJournal of the American Chemical Society-
dc.citation.titleJournal of the American Chemical Society-
dc.citation.volume144-
dc.citation.number25-
dc.citation.startPage11238-
dc.citation.endPage11245-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusSELF-ASSEMBLED MONOLAYERS-
dc.subject.keywordPlusGOLD-
dc.subject.keywordPlusNANOPARTICLES-
dc.subject.keywordPlusSURFACE-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusMECHANISM-
dc.subject.keywordPlusNANOZYMES-
dc.subject.keywordPlusMULTIVALENT-
Appears in Collections:
Center for Soft and Living Matter(첨단연성물질 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
There are no files associated with this item.

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse