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An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

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Title
An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation
Author(s)
Sharma, Anuja; Sangho So; Jun-Hyeong Kim; MacMillan, Samantha N.; Mu-Hyun Baik; Trovitch, Ryan J.
Publication Date
2022-09
Journal
CHEMICAL COMMUNICATIONS, v.58, no.77, pp.10793 - 10796
Publisher
ROYAL SOC CHEMISTRY
Abstract
Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, ((Ph)(2)PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s(-1) is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.
URI
https://pr.ibs.re.kr/handle/8788114/12358
DOI
10.1039/d2cc04089a
ISSN
1359-7345
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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