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분자활성 촉매반응 연구단
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Iridium-catalyzed direct arene C-H bond amidation with sulfonyl- and aryl azides

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Title
Iridium-catalyzed direct arene C-H bond amidation with sulfonyl- and aryl azides
Author(s)
Donggun Lee; Youngchan Kim; Sukbok Chang
Publication Date
2013-11
Journal
JOURNAL OF ORGANIC CHEMISTRY, v.78, no.21, pp.11102 - 11109
Publisher
AMER CHEMICAL SOC
Abstract
Iridium-catalyzed direct ortho C-H amidation of arenes has been shown to work well with sulfonyl- and aryl azides as the nitrogen source. The reaction proceeds efficiently with a broad range of substrates bearing conventional directing groups with excellent functional group compatibility under mild conditions. In addition, substrates forming not only 5- but also 6-membered iridacycle intermediates undergo the C-H amidation with high selectivity. © 2013 American Chemical Society.
URI
https://pr.ibs.re.kr/handle/8788114/1214
ISSN
0022-3263
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
Files in This Item:
Iridium-CatalyzedDirectAreneC-HBondAmidationwithSulfonyl-andArylAzides.pdfDownload

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