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Qiu, Lu
다차원 탄소재료 연구단
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Dynamic State and Active Structure of Ni–Co Catalyst in Carbon Nanofiber Growth Revealed by in Situ Transmission Electron Microscopy

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Title
Dynamic State and Active Structure of Ni–Co Catalyst in Carbon Nanofiber Growth Revealed by in Situ Transmission Electron Microscopy
Author(s)
Fan, Hua; Lu Qiu; Fedorov, Alexey; Willinger, Marc-Georg; Feng Ding; Huang, Xing
Publication Date
2021-11
Journal
ACS Nano, v.15, no.11, pp.17895 - 17906
Publisher
American Chemical Society
Abstract
Alloy catalysts often show superior effectiveness in the growth of carbon nanotubes/nanofibers (CNTs/CNFs) as compared to monometallic catalysts. However, due to the lack of an understanding of the active state and active structure, the origin of the superior performance of alloy catalysts is unknown. In this work, we report an in situ transmission electron microscopy (TEM) study of the CNF growth enabled by one of the most active known alloy catalysts, i.e., Ni–Co, providing insights into the active state and the interaction between Ni and Co in the working catalyst. We reveal that the functioning catalyst is highly dynamic, undergoing constant reshaping and periodic elongation/contraction. Atomic-scale imaging combined with in situ electron energy-loss spectroscopy further identifies the active structure as a Ni–Co metallic alloy (face-centered cubic, FCC). Aided by the molecular dynamics simulation and density functional theory calculations, we rationalize the dynamic behavior of the catalyst and the growth mechanism of CNFs and provide insight into the origin of the superior performance of the Ni–Co alloy catalyst.
URI
https://pr.ibs.re.kr/handle/8788114/12083
DOI
10.1021/acsnano.1c06189
ISSN
1936-0851
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
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