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Iridium-catalyzed direct C-H amidation with weakly coordinating carbonyl directing groups under mild conditions

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Title
Iridium-catalyzed direct C-H amidation with weakly coordinating carbonyl directing groups under mild conditions
Author(s)
Jinwoo Kim; Sukbok Chang
Subject
Amidation, ; azides, ; Directing groups, ; Ketone group, ; Lithium carbonates, ; Reaction efficiency, ; weakly coordinating groups, ; Catalysis, ; Esterification, ; Esters, ; Ketones, ; Iridium
Publication Date
2014-02
Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.53, no.8, pp.2203 - 2207
Publisher
WILEY-V C H VERLAG GMBH
Abstract
An iridium-catalyzed direct C-H amidation of weakly coordinating substrates, in particular of those bearing ester and ketone groups, under very mild conditions has been developed. The observed high reaction efficiency was achieved by the combined use of acetic acid and lithium carbonate as additives. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
URI
https://pr.ibs.re.kr/handle/8788114/1120
DOI
10.1002/anie.201310544
ISSN
1433-7851
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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