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분자활성 촉매반응 연구단
분자활성 촉매반응 연구단
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Orthogonal reactivity of acyl azides in C-H activation: Dichotomy between C-C and C-N amidations based on catalyst systems Highly Cited Paper

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Title
Orthogonal reactivity of acyl azides in C-H activation: Dichotomy between C-C and C-N amidations based on catalyst systems
Author(s)
Kwangmin Shin; Jaeyune Ryu; Sukbok Chang
Publication Date
2014-04
Journal
ORGANIC LETTERS, v.16, no.7, pp.2022 - 2025
Publisher
AMER CHEMICAL SOC
Abstract
The dual reactivity of acyl azides was utilized successfully in C-H activation by the choice of catalyst systems: while selective C-C amidation was achieved under thermal Rh catalysis, a Ru catalyst was found to mediate direct C-N amidation also highly selectively. Investigations of the mechanistic dichotomy between two catalytic systems are also presented. © 2014 American Chemical Society.
URI
https://pr.ibs.re.kr/handle/8788114/1082
ISSN
1523-7060
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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