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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Iridium-Catalyzed C-H Amination with Anilines at Room Temperature: Compatibility of Iridacycles with External Oxidants
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- Title
- Iridium-Catalyzed C-H Amination with Anilines at Room Temperature: Compatibility of Iridacycles with External Oxidants
- Author(s)
- Hyunwoo Kim; Kwangmin Shin; Suk Bok Chang
- Subject
- Aniline, ; Catalysis, ; Oxidants, ; Benzamides, ; C-H amination, ; Catalyst system, ; Isolation and characterization, ; Room temperature, ; Iridium, ; aniline, ; benzamide derivative, ; iridium, ; oxidizing agent, ; amination, ; article, ; catalysis, ; catalyst, ; hydrogen bond, ; reaction analysis, ; reaction optimization, ; room temperature
- Publication Date
- 2014-04
- Journal
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.136, no.16, pp.5904 - 5907
- Publisher
- AMER CHEMICAL SOC
- Abstract
- Described herein is the development of an iridium-catalyzed direct C-H amination of benzamides with anilines at room temperature, representing a unique example of an Ir catalyst system that is compatible with external oxidants. Mechanistic details, such as the isolation and characterization of key iridacycle intermediates, are also discussed. © 2014 American Chemical Society.
- ISSN
- 0002-7863
- Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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