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나노물질및화학반응연구단
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2,2′-dihydroxybenzil: A stereodynamic probe for primary amines controlled by steric strain

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dc.contributor.authorMin-Seob Seo-
dc.contributor.authorAnsoo Lee-
dc.contributor.authorHyunwoo Kim-
dc.date.available2015-04-20T05:53:32Z-
dc.date.created2014-09-11-
dc.date.issued2014-06-
dc.identifier.issn1523-7060-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/1020-
dc.description.abstractA rational approach for generating 1,1′-binaphthalene-like axial chirality of a small organic receptor, 2,2′-dihydroxybenzil is presented. The receptor combines with 2 equiv of monodentate primary amines to form a diimine, of which axial chirality is controlled by steric strain with moderate (1.4:1) to good (4.7:1) stereoselectivity. The observed circular dichroism (CD) spectra have been closely simulated by TD-DFT computations and can be used for determining the absolute chirality and enantiomeric excess of primary amines. © 2014 American Chemical Society.-
dc.description.uri1-
dc.language영어-
dc.publisherAMER CHEMICAL SOC-
dc.title2,2′-dihydroxybenzil: A stereodynamic probe for primary amines controlled by steric strain-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000337074300043-
dc.identifier.scopusid2-s2.0-84902083809-
dc.identifier.rimsid53613ko
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorMin-Seob Seo-
dc.contributor.affiliatedAuthorAnsoo Lee-
dc.contributor.affiliatedAuthorHyunwoo Kim-
dc.identifier.doi10.1021/ol501088v-
dc.identifier.bibliographicCitationORGANIC LETTERS, v.16, no.11, pp.2950 - 2953-
dc.citation.titleORGANIC LETTERS-
dc.citation.volume16-
dc.citation.number11-
dc.citation.startPage2950-
dc.citation.endPage2953-
dc.date.scptcdate2018-10-01-
dc.description.wostc15-
dc.description.scptc15-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > 1. Journal Papers (저널논문)
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