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Nickel-catalyzed polymerization of a substituted sulfoxonium ylide

DC Field Value Language
dc.contributor.authorSherilyn J. Lu-
dc.contributor.authorSongsu Kang-
dc.contributor.authorYoungsang Cho-
dc.contributor.authorMinseok Choi-
dc.contributor.authorChristopher W. Bielawski-
dc.date.accessioned2021-09-06T05:50:03Z-
dc.date.accessioned2021-09-06T05:50:03Z-
dc.date.available2021-09-06T05:50:03Z-
dc.date.available2021-09-06T05:50:03Z-
dc.date.created2021-07-07-
dc.date.issued2021-08-15-
dc.identifier.issn2642-4169-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/10193-
dc.description.abstract© 2021 The Authors. Journal of Polymer Science published by Wiley Periodicals LLC.The homopolymerization of (dimethylamino)phenylsulfoxonium ethylide, a substituted sulfoxonium ylide, is reported. Treatment of the monomer with a readily available Ni(II) catalyst afforded poly[(1-butene)-ran-(2-butene)-ran-(ethylene)] in good yield and high molecular weight. Varying the initial monomer-to-catalyst feed ratio enabled control over the molecular weights of the polymers produced. The polymerization mechanism appears to proceed in a chain growth fashion that entails the addition of ethylide units to growing polymer chains in conjunction with the expulsion of (dimethylamino)phenyl sulfoxide as a byproduct.-
dc.language영어-
dc.publisherJohn Wiley and Sons Inc-
dc.titleNickel-catalyzed polymerization of a substituted sulfoxonium ylide-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000662028400001-
dc.identifier.scopusid2-s2.0-85108065540-
dc.identifier.rimsid75937-
dc.contributor.affiliatedAuthorSherilyn J. Lu-
dc.contributor.affiliatedAuthorSongsu Kang-
dc.contributor.affiliatedAuthorYoungsang Cho-
dc.contributor.affiliatedAuthorChristopher W. Bielawski-
dc.identifier.doi10.1002/pol.20210228-
dc.identifier.bibliographicCitationJOURNAL OF POLYMER SCIENCE, v.59, no.16, pp.1787 - 1794-
dc.relation.isPartOfJOURNAL OF POLYMER SCIENCE-
dc.citation.titleJOURNAL OF POLYMER SCIENCE-
dc.citation.volume59-
dc.citation.number16-
dc.citation.startPage1787-
dc.citation.endPage1794-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaPolymer Science-
dc.relation.journalWebOfScienceCategoryPolymer Science-
dc.subject.keywordPlusMEDIATED POLYMERIZATION-
dc.subject.keywordPlusRADICAL POLYMERIZATION-
dc.subject.keywordPlusC1 POLYMERIZATION-
dc.subject.keywordPlusPOLYMETHYLENE-
dc.subject.keywordPlusPOLYHOMOLOGATION.-
dc.subject.keywordPlusDIAZOALKANES-
dc.subject.keywordPlusMECHANISM-
dc.subject.keywordPlusPOLYMERS-
dc.subject.keywordPlusCOMPLEX-
dc.subject.keywordAuthorC1 polymerization-
dc.subject.keywordAuthornickel catalyst-
dc.subject.keywordAuthorpoly(methyl methylene)-
dc.subject.keywordAuthorpolyhomologation-
dc.subject.keywordAuthorSulfoxonium ylides-
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
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