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Ring Opening Metathesis Polymerization of Cyclic Allenes

DC Field Value Language
dc.contributor.authorGeonhui Park-
dc.contributor.authorChristopher W. Bielawski-
dc.date.accessioned2021-08-12T05:30:15Z-
dc.date.accessioned2021-08-12T05:30:15Z-
dc.date.available2021-08-12T05:30:15Z-
dc.date.available2021-08-12T05:30:15Z-
dc.date.created2021-08-09-
dc.date.issued2021-07-13-
dc.identifier.issn0024-9297-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/10104-
dc.description.abstractThe ring opening metathesis polymerization of cyclic allenes is described. Treating the monomers to a Grubbs-type catalyst afforded polymers that featured allenes integrated into their main chains, as confirmed through a range of spectroscopic, chromatographic, and chemical techniques. Acyclic, 1,3-disubstituted allenes were used as chain transfer agents in the aforementioned reactions. These additives not only provided the corresponding end-functionalized polymers but also enabled control over the molecular weights of the polymers produced. The polymers obtained from the ring opening metathesis polymerization reactions were transformed into silyl-containing derivatives using a hydrosilylation-based, post-polymerization modification. A polymerization mechanism was also deduced and proposed to proceed through a process that involved ruthenium vinylidene intermediates and selective chain transfer.-
dc.language영어-
dc.publisherAMER CHEMICAL SOC-
dc.titleRing Opening Metathesis Polymerization of Cyclic Allenes-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000674278700025-
dc.identifier.scopusid2-s2.0-85110332691-
dc.identifier.rimsid76125-
dc.contributor.affiliatedAuthorGeonhui Park-
dc.contributor.affiliatedAuthorChristopher W. Bielawski-
dc.identifier.doi10.1021/acs.macromol.1c00571-
dc.identifier.bibliographicCitationMACROMOLECULES, v.54, no.13, pp.6135 - 6143-
dc.relation.isPartOfMACROMOLECULES-
dc.citation.titleMACROMOLECULES-
dc.citation.volume54-
dc.citation.number13-
dc.citation.startPage6135-
dc.citation.endPage6143-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaPolymer Science-
dc.relation.journalWebOfScienceCategoryPolymer Science-
dc.subject.keywordPlusLIVING COORDINATION POLYMERIZATION-
dc.subject.keywordPlusCHAIN-TRANSFER-
dc.subject.keywordPlusCATIONIC-POLYMERIZATION-
dc.subject.keywordPlusRADICAL POLYMERIZATION-
dc.subject.keywordPlusRUTHENIUM CATALYSTS-
dc.subject.keywordPlusIN-SITU-
dc.subject.keywordPlusHYDROSILYLATION-
dc.subject.keywordPlusROMP-
dc.subject.keywordPlusPHENYLALLENE-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordAuthorAllenes-
dc.subject.keywordAuthorMonomers-
dc.subject.keywordAuthorPolymerization-
dc.subject.keywordAuthorCatalysts-
dc.subject.keywordAuthorPolymers-
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
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