Enantioselective Access to Spirolactams via Nitrenoid Transfer Enabled by Enhanced Noncovalent Interactions
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Euijae Lee | - |
dc.contributor.author | Yeongyu Hwang | - |
dc.contributor.author | Yeong Bum Kim | - |
dc.contributor.author | Dongwook Kim | - |
dc.contributor.author | Sukbok Chang | - |
dc.date.accessioned | 2021-05-27T00:30:12Z | - |
dc.date.accessioned | 2021-05-27T00:30:13Z | - |
dc.date.available | 2021-05-27T00:30:12Z | - |
dc.date.available | 2021-05-27T00:30:13Z | - |
dc.date.created | 2021-05-26 | - |
dc.date.issued | 2021-05-05 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/9695 | - |
dc.description.abstract | Described herein is the Ir-catalyzed enantioselective access to chiral spirolactam products via the nitrenoid transfer to aromatic ipso-carbons. The key strategy for precise stereocontrol is to enhance the secondary attractive and repulsive interactions between the chiral catalyst and substrates by the introduction of a traceless O-silyl achiral auxiliary, thus effectively differentiating two prochiral faces of arenol-derived 1,4,2-dioxazol-5-one substrates. | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Enantioselective Access to Spirolactams via Nitrenoid Transfer Enabled by Enhanced Noncovalent Interactions | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000648704100009 | - |
dc.identifier.scopusid | 2-s2.0-85106068769 | - |
dc.identifier.rimsid | 75612 | - |
dc.contributor.affiliatedAuthor | Euijae Lee | - |
dc.contributor.affiliatedAuthor | Yeongyu Hwang | - |
dc.contributor.affiliatedAuthor | Yeong Bum Kim | - |
dc.contributor.affiliatedAuthor | Dongwook Kim | - |
dc.contributor.affiliatedAuthor | Sukbok Chang | - |
dc.identifier.doi | 10.1021/jacs.1c02550 | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.143, no.17, pp.6363 - 6369 | - |
dc.relation.isPartOf | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 143 | - |
dc.citation.number | 17 | - |
dc.citation.startPage | 6363 | - |
dc.citation.endPage | 6369 | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | PHENOLS | - |
dc.subject.keywordPlus | ASYMMETRIC DEAROMATIZATION | - |
dc.subject.keywordPlus | OXIDATIVE SPIROLACTONIZATION | - |
dc.subject.keywordPlus | GAMMA-LACTAMS | - |
dc.subject.keywordPlus | AMINATION | - |
dc.subject.keywordPlus | AZIRIDINATION | - |
dc.subject.keywordPlus | SULFONAMIDES | - |
dc.subject.keywordPlus | 2-NAPHTHOLS | - |
dc.subject.keywordPlus | NAPHTHOLS | - |