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분자활성 촉매반응 연구단
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Enantioselective Access to Spirolactams via Nitrenoid Transfer Enabled by Enhanced Noncovalent Interactions

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dc.contributor.authorEuijae Lee-
dc.contributor.authorYeongyu Hwang-
dc.contributor.authorYeong Bum Kim-
dc.contributor.authorDongwook Kim-
dc.contributor.authorSukbok Chang-
dc.date.accessioned2021-05-27T00:30:12Z-
dc.date.accessioned2021-05-27T00:30:13Z-
dc.date.available2021-05-27T00:30:12Z-
dc.date.available2021-05-27T00:30:13Z-
dc.date.created2021-05-26-
dc.date.issued2021-05-05-
dc.identifier.issn0002-7863-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/9695-
dc.description.abstractDescribed herein is the Ir-catalyzed enantioselective access to chiral spirolactam products via the nitrenoid transfer to aromatic ipso-carbons. The key strategy for precise stereocontrol is to enhance the secondary attractive and repulsive interactions between the chiral catalyst and substrates by the introduction of a traceless O-silyl achiral auxiliary, thus effectively differentiating two prochiral faces of arenol-derived 1,4,2-dioxazol-5-one substrates.-
dc.language영어-
dc.publisherAMER CHEMICAL SOC-
dc.titleEnantioselective Access to Spirolactams via Nitrenoid Transfer Enabled by Enhanced Noncovalent Interactions-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000648704100009-
dc.identifier.scopusid2-s2.0-85106068769-
dc.identifier.rimsid75612-
dc.contributor.affiliatedAuthorEuijae Lee-
dc.contributor.affiliatedAuthorYeongyu Hwang-
dc.contributor.affiliatedAuthorYeong Bum Kim-
dc.contributor.affiliatedAuthorDongwook Kim-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1021/jacs.1c02550-
dc.identifier.bibliographicCitationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.143, no.17, pp.6363 - 6369-
dc.relation.isPartOfJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.citation.titleJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.citation.volume143-
dc.citation.number17-
dc.citation.startPage6363-
dc.citation.endPage6369-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusPHENOLS-
dc.subject.keywordPlusASYMMETRIC DEAROMATIZATION-
dc.subject.keywordPlusOXIDATIVE SPIROLACTONIZATION-
dc.subject.keywordPlusGAMMA-LACTAMS-
dc.subject.keywordPlusAMINATION-
dc.subject.keywordPlusAZIRIDINATION-
dc.subject.keywordPlusSULFONAMIDES-
dc.subject.keywordPlus2-NAPHTHOLS-
dc.subject.keywordPlusNAPHTHOLS-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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