IBS Publications Repository: Cobalt-Hydride-Catalyzed Hydrosilylation of 3-Alkynes Accompanying pi-Bond Migration

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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Cobalt-Hydride-Catalyzed Hydrosilylation of 3-Alkynes Accompanying pi-Bond Migration

DC Field	Value	Language
dc.contributor.author	Yeong Bum Kim	-
dc.contributor.author	Dongwook Kim	-
dc.contributor.author	Shashikant U. Dighe	-
dc.contributor.author	Sukbok Chang	-
dc.contributor.author	Jung-Woo Park	-
dc.date.accessioned	2021-04-27T07:30:40Z	-
dc.date.accessioned	2021-04-27T07:30:40Z	-
dc.date.available	2021-04-27T07:30:40Z	-
dc.date.available	2021-04-27T07:30:40Z	-
dc.date.created	2021-02-23	-
dc.date.issued	2021-02-05	-
dc.identifier.issn	2155-5435	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/9554	-
dc.description.abstract	We describe a protocol for cobalt-catalyzed hydrosilylation of 3-alkynes with accompanying pi-bond migration. Mechanistic studies indicate that (i) cobalt(I)-hydride bearing a bulky bisphosphine ligand is the key intermediate and (ii) is-bond migration occurs prior to hydrosilylation. The cascade process selectively furnishes terminal branched allylsilanes under mild conditions.	-
dc.language	영어	-
dc.publisher	AMER CHEMICAL SOC	-
dc.title	Cobalt-Hydride-Catalyzed Hydrosilylation of 3-Alkynes Accompanying pi-Bond Migration	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000618540300042	-
dc.identifier.scopusid	2-s2.0-85099950971	-
dc.identifier.rimsid	74555	-
dc.contributor.affiliatedAuthor	Yeong Bum Kim	-
dc.contributor.affiliatedAuthor	Dongwook Kim	-
dc.contributor.affiliatedAuthor	Shashikant U. Dighe	-
dc.contributor.affiliatedAuthor	Sukbok Chang	-
dc.contributor.affiliatedAuthor	Jung-Woo Park	-
dc.identifier.doi	10.1021/acscatal.0c05424	-
dc.identifier.bibliographicCitation	ACS CATALYSIS, v.11, no.3, pp.1548 - 1553	-
dc.relation.isPartOf	ACS CATALYSIS	-
dc.citation.title	ACS CATALYSIS	-
dc.citation.volume	11	-
dc.citation.number	3	-
dc.citation.startPage	1548	-
dc.citation.endPage	1553	-
dc.type.docType	Article	-
dc.description.journalClass	1	-
dc.description.journalClass	1	-
dc.description.isOpenAccess	N	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.relation.journalResearchArea	Chemistry	-
dc.relation.journalWebOfScienceCategory	Chemistry, Physical	-
dc.subject.keywordAuthor	cobalt	-
dc.subject.keywordAuthor	alkyne	-
dc.subject.keywordAuthor	hydrosilylation	-
dc.subject.keywordAuthor	alkyne	-
dc.subject.keywordAuthor	allylsilane	-
dc.subject.keywordAuthor	pi-bond migration	-