BROWSE

Related Scientist

cchf's photo.

cchf
분자활성촉매반응연구단
more info

ITEM VIEW & DOWNLOAD

Cobalt-Hydride-Catalyzed Hydrosilylation of 3-Alkynes Accompanying pi-Bond Migration

DC Field Value Language
dc.contributor.authorYeong Bum Kim-
dc.contributor.authorDongwook Kim-
dc.contributor.authorShashikant U. Dighe-
dc.contributor.authorSukbok Chang-
dc.contributor.authorJung-Woo Park-
dc.date.accessioned2021-04-27T07:30:40Z-
dc.date.accessioned2021-04-27T07:30:40Z-
dc.date.available2021-04-27T07:30:40Z-
dc.date.available2021-04-27T07:30:40Z-
dc.date.created2021-02-23-
dc.date.issued2021-02-05-
dc.identifier.issn2155-5435-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/9554-
dc.description.abstractWe describe a protocol for cobalt-catalyzed hydrosilylation of 3-alkynes with accompanying pi-bond migration. Mechanistic studies indicate that (i) cobalt(I)-hydride bearing a bulky bisphosphine ligand is the key intermediate and (ii) is-bond migration occurs prior to hydrosilylation. The cascade process selectively furnishes terminal branched allylsilanes under mild conditions.-
dc.language영어-
dc.publisherAMER CHEMICAL SOC-
dc.titleCobalt-Hydride-Catalyzed Hydrosilylation of 3-Alkynes Accompanying pi-Bond Migration-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000618540300042-
dc.identifier.scopusid2-s2.0-85099950971-
dc.identifier.rimsid74555-
dc.contributor.affiliatedAuthorYeong Bum Kim-
dc.contributor.affiliatedAuthorDongwook Kim-
dc.contributor.affiliatedAuthorShashikant U. Dighe-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.contributor.affiliatedAuthorJung-Woo Park-
dc.identifier.doi10.1021/acscatal.0c05424-
dc.identifier.bibliographicCitationACS CATALYSIS, v.11, no.3, pp.1548 - 1553-
dc.relation.isPartOfACS CATALYSIS-
dc.citation.titleACS CATALYSIS-
dc.citation.volume11-
dc.citation.number3-
dc.citation.startPage1548-
dc.citation.endPage1553-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.subject.keywordAuthorcobalt-
dc.subject.keywordAuthoralkyne-
dc.subject.keywordAuthorhydrosilylation-
dc.subject.keywordAuthoralkyne-
dc.subject.keywordAuthorallylsilane-
dc.subject.keywordAuthorpi-bond migration-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
There are no files associated with this item.

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse