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Kim, Kiho
분자활성 촉매반응 연구단
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Visible Light-Induced Intramolecular CO Bond Formation via 1,5-Hydrogen Atom Transfer Strategy

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Title
Visible Light-Induced Intramolecular CO Bond Formation via 1,5-Hydrogen Atom Transfer Strategy
Author(s)
Kim, Kiho; Kim, Namhoon; Hong, Sungwoo
Publication Date
2021-03
Journal
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.42, no.3, pp.548 - 552
Publisher
WILEY-V C H VERLAG GMBH
Abstract
An efficient strategy for the visible-light-promoted intramolecular CO bond formation has been accomplished, which allows the synthesis of cyclic ether derivatives in the absence of a photocatalyst. This reaction is likely to occur through the generation of alkoxy radical from in situ generated OI bond, followed by 1,5-hydrogen atom transfer (1,5-HAT) and subsequent intramolecular cyclization to form a CO bond. This synthetic approach offers an efficient tool by providing access to valuable cyclic ether scaffolds under mild reaction conditions.
URI
https://pr.ibs.re.kr/handle/8788114/9439
DOI
10.1002/bkcs.12234
ISSN
0253-2964
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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