IBS Publications Repository: Modular Tuning of Electrophilic Reactivity of Iridium Nitrenoids for the Intermolecular Selective α-Amidation of β-Keto Esters

BROWSE

Related Scientist

cchf's photo.

cchf: 분자활성촉매반응연구단

ITEM VIEW & DOWNLOAD

IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Modular Tuning of Electrophilic Reactivity of Iridium Nitrenoids for the Intermolecular Selective α-Amidation of β-Keto Esters

DC Field	Value	Language
dc.contributor.author	Minhan Lee	-
dc.contributor.author	Hoimin Jung	-
dc.contributor.author	Dongwook Kim	-
dc.contributor.author	Jung-Woo Park	-
dc.contributor.author	Sukbok Chang	-
dc.date.accessioned	2020-12-22T02:57:08Z	-
dc.date.accessioned	2020-12-22T02:57:08Z	-
dc.date.available	2020-12-22T02:57:08Z	-
dc.date.available	2020-12-22T02:57:08Z	-
dc.date.created	2020-09-09	-
dc.date.issued	2020-07	-
dc.identifier.issn	0002-7863	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/7759	-
dc.description.abstract	© 2020 American Chemical Society We report herein an Ir-catalyzed intermolecular amino group transfer to β-keto esters (amides) to access α-aminocarbonyl products with excellent chemoselectivity. The key strategy was to engineer electrophilicity of the putative Ir-nitrenoids by tuning electronic property of the κ2-N,O chelating ligands, thus facilitating nucleophilic addition of enol π-bonds of 1,3-dicarbonyl substrates	-
dc.description.uri	1	-
dc.language	영어	-
dc.publisher	AMER CHEMICAL SOC	-
dc.subject	C-H AMINATION	-
dc.subject	CATALYZED AZIRIDINATION	-
dc.subject	GAMMA-LACTAMS	-
dc.subject	BONDS	-
dc.subject	FUNCTIONALIZATION	-
dc.subject	DERIVATIVES	-
dc.subject	STRATEGY	-
dc.subject	ACCESS	-
dc.title	Modular Tuning of Electrophilic Reactivity of Iridium Nitrenoids for the Intermolecular Selective α-Amidation of β-Keto Esters	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000551495700010	-
dc.identifier.scopusid	2-s2.0-85088177297	-
dc.identifier.rimsid	72827	-
dc.contributor.affiliatedAuthor	Minhan Lee	-
dc.contributor.affiliatedAuthor	Hoimin Jung	-
dc.contributor.affiliatedAuthor	Dongwook Kim	-
dc.contributor.affiliatedAuthor	Jung-Woo Park	-
dc.contributor.affiliatedAuthor	Sukbok Chang	-
dc.identifier.doi	10.1021/jacs.0c04344	-
dc.identifier.bibliographicCitation	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.142, no.28, pp.11999 - 12004	-
dc.citation.title	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY	-
dc.citation.volume	142	-
dc.citation.number	28	-
dc.citation.startPage	11999	-
dc.citation.endPage	12004	-
dc.description.journalClass	1	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.subject.keywordPlus	C-H AMINATION	-
dc.subject.keywordPlus	CATALYZED AZIRIDINATION	-
dc.subject.keywordPlus	GAMMA-LACTAMS	-
dc.subject.keywordPlus	BONDS	-
dc.subject.keywordPlus	FUNCTIONALIZATION	-
dc.subject.keywordPlus	DERIVATIVES	-
dc.subject.keywordPlus	STRATEGY	-
dc.subject.keywordPlus	ACCESS	-