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분자활성 촉매반응 연구단
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Reductive activation of PdII-precatalysts: Via decarboxylation of pivalate in direct C-H arylation reactions

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dc.contributor.authorSeoung-Tae Kim-
dc.contributor.authorMu-Hyun Baik-
dc.date.accessioned2020-12-22T02:23:50Z-
dc.date.accessioned2020-12-22T02:23:50Z-
dc.date.available2020-12-22T02:23:50Z-
dc.date.available2020-12-22T02:23:50Z-
dc.date.created2020-12-03-
dc.date.issued2020-11-
dc.identifier.issn1359-7345-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/7551-
dc.description.abstract© The Royal Society of Chemistry 2020.The mechanism of the reductive activation of PdII pre-catalysts has been extensively studied, but remains poorly understood. Herein, a combined computational and experimental approach is employed to clearly identify a PdII reduction process that has not been considered thus far. Pivalate, assumed to be a general base, was found to decarboxylate and act as a reductant, suggesting an alternative explanation for the superior performance of pivalic acid as an additive in Pd-catalyzed direct C-H arylation reactions-
dc.description.uri1-
dc.language영어-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectAlkenylation-
dc.subject8-Aminoquinoline-
dc.subjectRhodium-
dc.titleReductive activation of PdII-precatalysts: Via decarboxylation of pivalate in direct C-H arylation reactions-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000588197200032-
dc.identifier.scopusid2-s2.0-85096061895-
dc.identifier.rimsid73827-
dc.contributor.affiliatedAuthorSeoung-Tae Kim-
dc.contributor.affiliatedAuthorMu-Hyun Baik-
dc.identifier.doi10.1039/d0cc06085b-
dc.identifier.bibliographicCitationCHEMICAL COMMUNICATIONS, v.56, no.89, pp.13868 - 13871-
dc.citation.titleCHEMICAL COMMUNICATIONS-
dc.citation.volume56-
dc.citation.number89-
dc.citation.startPage13868-
dc.citation.endPage13871-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordPlusCATALYZED COUPLING REACTIONS-
dc.subject.keywordPlusZEROVALENT PALLADIUM-
dc.subject.keywordPlusARYL HALIDES-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusMECHANISM-
dc.subject.keywordPlusDEHALOGENATION-
dc.subject.keywordPlusPD(OAC)(2)-
dc.subject.keywordPlusOXIDATION-
dc.subject.keywordPlusMIXTURES-
dc.subject.keywordPlusRATES-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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