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분자활성 촉매반응 연구단
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Functionalization of Pyridinium Derivatives with 1,4-Dihydropyridines Enabled by Photoinduced Charge Transfer

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dc.contributor.authorInwon Kim-
dc.contributor.authorSeongjin Park-
dc.contributor.authorSunwoo Hong-
dc.date.accessioned2020-12-22T02:23:45Z-
dc.date.accessioned2020-12-22T02:23:45Z-
dc.date.available2020-12-22T02:23:45Z-
dc.date.available2020-12-22T02:23:45Z-
dc.date.created2020-12-03-
dc.date.issued2020-11-
dc.identifier.issn1523-7060-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/7548-
dc.description.abstract© 2020 American Chemical Society. By exploiting electron donor-acceptor (EDA) complexes between 1,4-dihydropyridines and N-amidopyridinium salts under visible light irradiation, we discovered that photoinduced intermolecular charge transfer induces a single-electron transfer event without requiring a photocatalyst for the facile functionalization of pyridines. The generality of this method is amenable to various types of 1,4-dihydropyridines radical precursors to generate structurally different radicals such as alkyl, acyl, and carbamoyl radicals, ultimately providing facile access to synthetically valuable C4-functionalized pyridines. A broad range of functional groups are well accommodated under mild and metal-free conditions, and the synthetic utility of the present method is showcased by the late-stage functionalization of a variety of biologically relevant pyridine-based compounds, pharmaceuticals, and peptide feedstocks-
dc.description.uri1-
dc.language영어-
dc.publisherAMER CHEMICAL SOC-
dc.titleFunctionalization of Pyridinium Derivatives with 1,4-Dihydropyridines Enabled by Photoinduced Charge Transfer-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000589942900103-
dc.identifier.scopusid2-s2.0-85095807464-
dc.identifier.rimsid73843-
dc.contributor.affiliatedAuthorInwon Kim-
dc.contributor.affiliatedAuthorSeongjin Park-
dc.contributor.affiliatedAuthorSunwoo Hong-
dc.identifier.doi10.1021/acs.orglett.0c03347-
dc.identifier.bibliographicCitationORGANIC LETTERS, v.22, no.21, pp.8730 - 8734-
dc.citation.titleORGANIC LETTERS-
dc.citation.volume22-
dc.citation.number21-
dc.citation.startPage8730-
dc.citation.endPage8734-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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