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분자활성촉매반응연구단
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Unexpected Selectivity of Intramolecular [3+2] Cycloaddition of Trimethylenemethane (TMM) Diyl toward Total Synthesis of Conidiogenone B

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dc.contributor.authorMyungjo J. Kim-
dc.contributor.authorLee Snaghyeon-
dc.contributor.authorKang Taek-
dc.contributor.authorBaik Mu-Hyun-
dc.contributor.authorLee Hee-Yoon-
dc.date.available2020-03-18T08:17:27Z-
dc.date.created2020-02-17-
dc.date.issued2020-02-
dc.identifier.issn1434-193X-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/7012-
dc.description.abstractIn the course of a study toward a total synthesis of conidiogenone B through TMM diyl-mediated tandem cycloaddition reaction, unexpected regioselectivity for a bridged isomer was observed. The synthetic and computational studies with model compounds revealed that regioselectivity can be rendered by changing substitution patterns on the TMM diyl moiety and the olefin moiety by altering the activation energy of cycloaddition reaction through a singlet TMM diyl pathway © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.description.uri1-
dc.language영어-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectNatural products-
dc.subjectTotal synthesis-
dc.subjectRegioselectivity-
dc.subjectRadicals-
dc.subjectDensity functional calculations-
dc.titleUnexpected Selectivity of Intramolecular [3+2] Cycloaddition of Trimethylenemethane (TMM) Diyl toward Total Synthesis of Conidiogenone B-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000509414700001-
dc.identifier.scopusid2-s2.0-85078727156-
dc.identifier.rimsid71341-
dc.contributor.affiliatedAuthorMyungjo J. Kim-
dc.contributor.affiliatedAuthorBaik Mu-Hyun-
dc.identifier.doi10.1002/ejoc.201901700-
dc.identifier.bibliographicCitationEUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2020, no.5, pp.609 - 617-
dc.citation.titleEUROPEAN JOURNAL OF ORGANIC CHEMISTRY-
dc.citation.volume2020-
dc.citation.number5-
dc.citation.startPage609-
dc.citation.endPage617-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordPlusTRAPPING REACTIONS-
dc.subject.keywordPlusDITERPENES-
dc.subject.keywordAuthorNatural products-
dc.subject.keywordAuthorTotal synthesis-
dc.subject.keywordAuthorRegioselectivity-
dc.subject.keywordAuthorRadicals-
dc.subject.keywordAuthorDensity functional calculations-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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