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On-surface Photochemistry of Pre-ordered 1-Methyl-2-phenyl-acetylenes: C-H Bond Activation and Intermolecular Coupling on Highly Oriented Pyrolytic Graphite

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Title
On-surface Photochemistry of Pre-ordered 1-Methyl-2-phenyl-acetylenes: C-H Bond Activation and Intermolecular Coupling on Highly Oriented Pyrolytic Graphite
Author(s)
Luciano Colazzo; Sambi, M; Sedona, F; Casarin, M
Publication Date
2019-09
Journal
CHEMPHYSCHEM, v.20, no.18, pp.2317 - 2321
Publisher
WILEY-V C H VERLAG GMBH
Abstract
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimIn this contribution we report on light-induced metal-free coupling of propynylbenzene molecular units on highly oriented pyrolytic graphite. The reaction occurs within the self-assembled monolayer and leads to the generation of covalently coupled 1,5-hexadiyne and para-terphenyl derivatives under topological control. Such photochemical uncatalysed pathway represents an original approach in the field of topological C−C coupling at the solid/liquid interface and provides new insight into the low temperature formation of aromatic compounds at the surface of carbonaceous supports
URI
https://pr.ibs.re.kr/handle/8788114/6878
ISSN
1439-4235
Appears in Collections:
Center for Quantum Nanoscience(양자나노과학 연구단) > Journal Papers (저널 논문)
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Luciano Colazzo_On-surface Photochemistry of Pre-ordered 1-Methyl-2-phenyl-acetylenes C-H Bond Activation and Intermolecular Coupling on Highly Oriented Pyrolytic Graphite_et_al-2019-ChemPhysChem.pdfDownload

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