BROWSE

Related Scientist

Researcher

Mahesh Sundararajan
분자활성 촉매반응 연구단
more info

Regioselective Oxidation of C-H Bonds in Unactivated Alkanes by a Vanadium Superoxo Catalyst Bound to a Supramolecular Host

Cited 0 time in webofscience Cited 0 time in scopus
20 Viewed 4 Downloaded
Title
Regioselective Oxidation of C-H Bonds in Unactivated Alkanes by a Vanadium Superoxo Catalyst Bound to a Supramolecular Host
Author(s)
Mahesh Sundararajan; Bohyun Park; Mu-Hyun Baik
Publication Date
2019-12
Journal
INORGANIC CHEMISTRY, v.58, no.23, pp.16250 - 16255
Publisher
AMER CHEMICAL SOC
Abstract
© 2019 American Chemical Society.A vanadyl ion bound to a cucurbituril (CB) host was reported to oxidize pentane to 2-pentanol in the presence of an oxidizer. DFT calculations suggest that the catalyst selectively reacts with stronger C-H bonds in pentane over weaker C-H bonds in cyclohexane due to size exclusion by the CB host. The active catalyst is an unprecedented vanadium superoxo species bound to the host, and the selectivity toward secondary over the primary C-H bond is the result of a higher degree of charge transfer from the secondary compared to the primary position
URI
https://pr.ibs.re.kr/handle/8788114/6731
ISSN
0020-1669
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
Files in This Item:
acs.inorgchem.pdfDownload

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse