IBS Publications Repository: Synthetic Utility of N-Benzoyloxyamides as an Alternative Precursor of Acylnitrenoids for γ-Lactam Formation

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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Synthetic Utility of N-Benzoyloxyamides as an Alternative Precursor of Acylnitrenoids for γ-Lactam Formation

DC Field	Value	Language
dc.contributor.author	Soohee Huh	-
dc.contributor.author	Seung Youn Hong	-
dc.contributor.author	Sukbok Chang	-
dc.date.available	2019-08-19T02:06:30Z	-
dc.date.created	2019-05-29	-
dc.date.issued	2019-04	-
dc.identifier.issn	1523-7060	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/5994	-
dc.description.abstract	Copyright © 2019 American Chemical Society. Described herein is the development of a new entry of acylnitrenoid precursors for γ-lactam synthesis via an intramolecular C-H amidation reaction. Upon Ir catalysis, N-benzoyloxyamides serve as efficient substrates to afford 5-membered amides. Mechanistic studies revealed that the generation of a putative Ir-carbonylnitrenoid via N-O bond cleavage is facilitated by the chelation of countercations. This protocol offers a convenient and step-economic route to γ-lactams starting from the corresponding carboxylic acids	-
dc.description.uri	1	-
dc.language	영어	-
dc.publisher	AMER CHEMICAL SOC	-
dc.title	Synthetic Utility of N-Benzoyloxyamides as an Alternative Precursor of Acylnitrenoids for γ-Lactam Formation	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000465644300067	-
dc.identifier.scopusid	2-s2.0-85064112448	-
dc.identifier.rimsid	68069	-
dc.contributor.affiliatedAuthor	Soohee Huh	-
dc.contributor.affiliatedAuthor	Seung Youn Hong	-
dc.contributor.affiliatedAuthor	Sukbok Chang	-
dc.identifier.doi	10.1021/acs.orglett.9b00791	-
dc.identifier.bibliographicCitation	ORGANIC LETTERS, v.21, no.8, pp.2808 - 2812	-
dc.citation.title	ORGANIC LETTERS	-
dc.citation.volume	21	-
dc.citation.number	8	-
dc.citation.startPage	2808	-
dc.citation.endPage	2812	-
dc.description.journalClass	1	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.subject.keywordPlus	C-H AMIDATION	-
dc.subject.keywordPlus	PROTECTED AMINES	-
dc.subject.keywordPlus	AMINATION	-
dc.subject.keywordPlus	CHEMISTRY	-
dc.subject.keywordPlus	MILD	-