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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Gold(I)-Catalyzed Hydroxy Group Assisted C(sp2)-H Alkylation of Enaminones with Diazo Compounds to Access 3-Alkyl Chromones
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- Title
- Gold(I)-Catalyzed Hydroxy Group Assisted C(sp2)-H Alkylation of Enaminones with Diazo Compounds to Access 3-Alkyl Chromones
- Author(s)
- Pradip N. Bagle; Manoj V. Mane; Shashank P. Sancheti; Amol B. Gade; Samir R. Shaikh; Mu-Hyun Baik; Nitin T. Patil
- Publication Date
- 2019-01
- Journal
- ORGANIC LETTERS, v.21, no.1, pp.335 - 339
- Publisher
- AMER CHEMICAL SOC
- Abstract
- A strategy for expedient synthesis of 3-substituted chromones from easily available o-hydroxyarylenaminones and diazo compounds has been developed. Carefully conducted experimental and computational studies led us to propose an uncommon mechanistic pathway involving the hydroxyl group assisted alkylation of enaminones with in situ generated gold carbenes. © 2018 American Chemical Society
- ISSN
- 1523-7060
- Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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