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Catalytic Alkyne Arylation Using Traceless Directing Groups

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Title
Catalytic Alkyne Arylation Using Traceless Directing Groups
Author(s)
Jung-Woo Park; Bubwoong Kang; Vy M. Dong
Publication Date
2018-08
Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.41, pp.13598 - 13602
Publisher
WILEY-V C H VERLAG GMBH
Abstract
By using Pd0/Mandyphos, we achieved a three-component aminoarylation of alkynes to generate enamines, which are then hydrolyzed to either α-arylphenones or α,α-diarylketones. This Pd-catalyzed method overcomes established known pathways to enable the use of amines as traceless directing groups for C−C bond formation. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinhei
URI
https://pr.ibs.re.kr/handle/8788114/5223
ISSN
1433-7851
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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