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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Palladium-Catalyzed Divergent Cyclopropanation by Regioselective Solvent-Driven C(sp3)?H Bond Activation
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Da Sol Chung | - |
| dc.contributor.author | Jae Sung Lee | - |
| dc.contributor.author | Ho Ryu | - |
| dc.contributor.author | Jiyong Park | - |
| dc.contributor.author | Hyunjoong Kim | - |
| dc.contributor.author | Joo Hyun Lee | - |
| dc.contributor.author | UBin Kim | - |
| dc.contributor.author | Won Koo Lee | - |
| dc.contributor.author | Mu-Hyun Baik | - |
| dc.contributor.author | Sang-gi Lee | - |
| dc.date.available | 2019-01-03T05:30:42Z | - |
| dc.date.created | 2018-11-22 | - |
| dc.date.issued | 2018-11 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/5068 | - |
| dc.description.abstract | Reported is a tandem palladium-catalyzed Heck/regioselective C(sp3)?H activation reaction for the divergent synthesis of spiro- and fused-cyclopropanated indolines from N-methallylated 2-bromoarylamides. The regioselectivity of the C?H bond activation in the ��-alkylPdII intermediate is controlled by the solvent used. DFT calculations suggest that the polarity of solvent molecules could influence the transition-state energy, leading to a bifurcation of the C?H bond activation in the ��-alkylPdII intermediate. (c) 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinhei | - |
| dc.description.uri | 1 | - |
| dc.language | 영어 | - |
| dc.publisher | WILEY-V C H VERLAG GMBH | - |
| dc.subject | C?H activation | - |
| dc.subject | heterocylces | - |
| dc.subject | palladium | - |
| dc.subject | reaction mechanisms | - |
| dc.subject | solvent effects | - |
| dc.title | Palladium-Catalyzed Divergent Cyclopropanation by Regioselective Solvent-Driven C(sp3)?H Bond Activation | - |
| dc.type | Article | - |
| dc.type.rims | ART | - |
| dc.identifier.wosid | 000453344500027 | - |
| dc.identifier.scopusid | 2-s2.0-85055508059 | - |
| dc.identifier.rimsid | 66119 | - |
| dc.contributor.affiliatedAuthor | Ho Ryu | - |
| dc.contributor.affiliatedAuthor | Jiyong Park | - |
| dc.contributor.affiliatedAuthor | Hyunjoong Kim | - |
| dc.contributor.affiliatedAuthor | Mu-Hyun Baik | - |
| dc.identifier.doi | 10.1002/anie.201809133 | - |
| dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.47, pp.15460 - 15464 | - |
| dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
| dc.citation.volume | 57 | - |
| dc.citation.number | 47 | - |
| dc.citation.startPage | 15460 | - |
| dc.citation.endPage | 15464 | - |
| dc.embargo.liftdate | 9999-12-31 | - |
| dc.embargo.terms | 9999-12-31 | - |
| dc.description.journalClass | 1 | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.subject.keywordAuthor | C?H activation | - |
| dc.subject.keywordAuthor | heterocylces | - |
| dc.subject.keywordAuthor | palladium | - |
| dc.subject.keywordAuthor | reaction mechanisms | - |
| dc.subject.keywordAuthor | solvent effects | - |
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- baik_et_al-2018-Angewandte(Palladium-Catalyzed).pdfDownload
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