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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Diels-Alder and Stille Coupling Approach for the Short Protecting-Group-Free Synthesis of Mycophenolic Acid, Its Phenylsulfenyl and Phenylselenyl Analogues, and Reactive Oxygen Species (ROS) Probing Capacity in Water
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- Title
- Diels-Alder and Stille Coupling Approach for the Short Protecting-Group-Free Synthesis of Mycophenolic Acid, Its Phenylsulfenyl and Phenylselenyl Analogues, and Reactive Oxygen Species (ROS) Probing Capacity in Water
- Publication Date
- 2018-06
- Journal
- ORGANIC LETTERS, v.20, no.12, pp.3557 - 3561
- Publisher
- AMER CHEMICAL SOC
- Abstract
- A short, protecting-group-free synthesis is achieved. The synthesis is step-efficient and general. A Diels-Alder and Stille cross-coupling approach includes key transformations, allowing for a competitive synthesis which involves a rare halophenol Stille cross-coupling study. The phenylselenyl and phenylsulfenyl analogues were prepared as novel compounds in good overall yield. The applicability of one of the intermediates as a potential probe for reactive oxygen species (ROS) in water is investigated. © 2018 American Chemical Society
- ISSN
- 1523-7060
- Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
- Files in This Item:
- acs.orglett.8b01327.pdfDownload
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