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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Piers' borane-mediated hydrosilylation of epoxides and cyclic ethers
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- Title
- Piers' borane-mediated hydrosilylation of epoxides and cyclic ethers
- Author(s)
- Jianbo Zhang; Sehoon Park; Sukbok Chang
- Publication Date
- 2018-07
- Journal
- CHEMICAL COMMUNICATIONS, v.54, no.52, pp.7243 - 7246
- Publisher
- ROYAL SOC CHEMISTRY
- Abstract
- We report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers' borane (C6F5)2BH with hydrosilanes in the presence of an epoxide revealed that an alkyloxy(diaryl)borane (C6F5)2BOR is readily formed as a catalytically competent species for the outer-sphere hydrosilylation of epoxides and cyclic ethers. © The Royal Society of Chemistry 2018
- ISSN
- 1359-7345
- Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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