Piers' borane-mediated hydrosilylation of epoxides and cyclic ethers

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Title
Piers' borane-mediated hydrosilylation of epoxides and cyclic ethers
Author(s)
Jianbo Zhang; Sehoon Park; Sukbok Chang
Publication Date
2018-07
Journal
CHEMICAL COMMUNICATIONS, v.54, no.52, pp.7243 - 7246
Publisher
ROYAL SOC CHEMISTRY
Abstract
We report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers' borane (C6F5)2BH with hydrosilanes in the presence of an epoxide revealed that an alkyloxy(diaryl)borane (C6F5)2BOR is readily formed as a catalytically competent species for the outer-sphere hydrosilylation of epoxides and cyclic ethers. © The Royal Society of Chemistry 2018
URI
https://pr.ibs.re.kr/handle/8788114/4949
ISSN
1359-7345
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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