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Rhodium-Catalyzed Direct C-H Phosphorylation of (Hetero)arenes Suitable for Late-Stage Functionalization

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Title
Rhodium-Catalyzed Direct C-H Phosphorylation of (Hetero)arenes Suitable for Late-Stage Functionalization
Author(s)
Minsik Min; Dahye Kang; Sungwoo Jung; Sungwoo Hong
Publication Date
2016-04
Journal
ADVANCED SYNTHESIS & CATALYSIS, v.358, no.8, pp.1296 - 1301
Publisher
WILEY-V C H VERLAG GMBH
Abstract
Efficient rhodium-catalyzed direct C-H phosphorylation of (hetero)arenes was developed. Various directing groups and a wide range of substrates, including heterocycles, can be utilized in this C-H phosphorylation process, allowing for the rapid installation of the phosphonate group into medicinally and biologically important privileged scaffolds. The efficient and straightforward method could serve as a new tool to streamline late-stage C-H functionalization for preparing aryl phosphonates, which are important structural motif in synthetic and medicinal chemistry (c) 2016 Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim
URI
https://pr.ibs.re.kr/handle/8788114/4842
ISSN
1615-4150
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
Files in This Item:
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