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Real nerve agent study assessing pyridyl reactivity: Selective fluorogenic and colorimetric detection of Soman and simulant

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Title
Real nerve agent study assessing pyridyl reactivity: Selective fluorogenic and colorimetric detection of Soman and simulant
Author(s)
Youngsam Kim; Yoon Jeong Jang; Dongyoul Lee; Byung-Sup Kim; David G. Churchill
Subject
Chemical warefare agent, ; Soman, ; Nerve agents, ; Fluorescent probe, ; BODIPY derivatives
Publication Date
2017-02
Journal
SENSORS AND ACTUATORS B-CHEMICAL, v.238, pp.145 - 149
Publisher
ELSEVIER SCIENCE SA
Abstract
Herein, a chemical probe is tested with live agents for the purpose of benchmarking fluorescent pyridyl-containing systems with actual nerve agents and simulants together. The molecule showed selective fluorogenic and colorimetric detection of Soman (GD) and its simulant over other G-series nerve agents and their simulants. H-1 and P-31 NMR spectroscopy and TD-DFT calculations help reveal the origin of the colorimetric and fluorogenic changes in the reacted system. (C) 2016 Elsevier B.V. All rights reserved
URI
https://pr.ibs.re.kr/handle/8788114/4818
DOI
10.1016/j.snb.2016.07.056
ISSN
0925-4005
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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