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Metal- and oxidant-free S-P(O) bond construction: Via direct coupling of P(O)H with sulfinic acids Highly Cited Paper

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Title
Metal- and oxidant-free S-P(O) bond construction: Via direct coupling of P(O)H with sulfinic acids
Author(s)
Youngtaek Moon; Yonghoon Moon; Hangyeol Choi; Sungwoo Hong
Publication Date
2017-02
Journal
GREEN CHEMISTRY, v.19, no.4, pp.1005 - 1013
Publisher
ROYAL SOC CHEMISTRY
Abstract
We have developed a simple and convenient method for S-P(O) bond formation between R2P(O)H and sulfinic acids under metal-, oxidant-, and halogen-free conditions. The current method is compatible with a broad range of substituents on various substrates including halogens and heterocyclic moieties. The synthetic potential of this method was further highlighted by the expeditious synthesis of optically active P-chiral phosphorothioates via stereospecific coupling. © 2017 The Royal Society of Chemistry
URI
https://pr.ibs.re.kr/handle/8788114/3961
ISSN
1463-9262
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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