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Visible light sensitization of benzoyl azides: Cascade cyclization toward oxindoles: Via a non-nitrene pathway

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Title
Visible light sensitization of benzoyl azides: Cascade cyclization toward oxindoles: Via a non-nitrene pathway
Author(s)
Dattatraya B. Bagal; Sung-Woo Park; Hyun-Ji Song; Sukbok Chang
Publication Date
2017-08
Journal
CHEMICAL COMMUNICATIONS, v.53, no.62, pp.8798 - 8801
Publisher
ROYAL SOC CHEMISTRY
Abstract
Visible light sensitization of benzoyl azides was examined in reaction with N-phenylmethacrylamides to afford biologically important oxindoles and spirooxindoles via a cascade cyclization under mild reaction conditions. Mechanistic studies suggested a non-nitrene pathway, where triplet benzoyl azides act as the reactive intermediate. © 2017 The Royal Society of Chemistry
URI
https://pr.ibs.re.kr/handle/8788114/3797
DOI
10.1039/c7cc04852a
ISSN
1359-7345
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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