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분자활성촉매반응연구단
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[4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the Cp Ligand

DC Field Value Language
dc.contributor.authorSeung Youn Hong-
dc.contributor.authorJisu Jeong-
dc.contributor.authorSukbok Chang-
dc.date.available2017-09-05T05:33:26Z-
dc.date.created2017-04-24-
dc.date.issued2017-02-
dc.identifier.issn1433-7851-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/3767-
dc.description.abstractA change in reaction pathway was achieved for the first time by tuning the cyclopentadienyl (Cp) ligand used for the rhodium-catalyzed cyclization of benzamides with conjugated enynones. Depending on the Cp ligand, the reaction pathway switched between [4+2] and [4+1] annulation. Electronic effects turned out to be crucial for the product distribution. The dichotomy was attributed to the alteration of the Lewis acidity of the resultant Cp-bound rhodium species. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.description.uri1-
dc.language영어-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectannulations-
dc.subjectcyclopentadienyl ligands-
dc.subjectreaction mechanisms-
dc.subjectrhodium catalysis-
dc.title[4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the Cp Ligand-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000395566600029-
dc.identifier.scopusid2-s2.0-85010425283-
dc.identifier.rimsid59221ko
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorSeung Youn Hong-
dc.contributor.affiliatedAuthorJisu Jeong-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1002/anie.201612559-
dc.identifier.bibliographicCitationANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.9, pp.2408 - 2412-
dc.citation.titleANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.citation.volume56-
dc.citation.number9-
dc.citation.startPage2408-
dc.citation.endPage2412-
dc.date.scptcdate2018-10-01-
dc.description.wostc38-
dc.description.scptc48-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordPlusC-H ACTIVATION-
dc.subject.keywordPlusN BOND FORMATION-
dc.subject.keywordPlusCYCLOPENTADIENYL LIGANDS-
dc.subject.keywordPlusAMBIENT CONDITIONS-
dc.subject.keywordPlusFACILE SYNTHESIS-
dc.subject.keywordPlusDIAZO-COMPOUNDS-
dc.subject.keywordPlusDIRECTING GROUP-
dc.subject.keywordPlusOXIME ESTERS-
dc.subject.keywordPlusALKENES-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordAuthorannulations-
dc.subject.keywordAuthorcyclopentadienyl ligands-
dc.subject.keywordAuthorreaction mechanisms-
dc.subject.keywordAuthorrhodium catalysis-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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