Direct azidation of isotactic polypropylene and synthesis of "grafted to' derivatives thereof using azide-alkyne cycloaddition chemistry
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Di Liu | - |
dc.contributor.author | Christopher W. Bielawski | - |
dc.date.available | 2017-01-26T05:17:01Z | - |
dc.date.created | 2017-01-16 | - |
dc.date.issued | 2017-01 | - |
dc.identifier.issn | 0959-8103 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/3327 | - |
dc.description.abstract | Azido-functionalized isotactic polypropylene was prepared via the direct CH azidation of a commercially available polymer using a stable azidoiodinane. Including imidazole or benzimidazole in the reaction mixture was found to significantly improve the yields of the post-polymerization modification. Although chain cleavage was observed, the methodology afforded high-molecular-weight (M-w>100 kDa) functionalized polypropylene containing up to 3mol% of azido groups and enabled access to polypropylene-graft-poly(ethylene glycol) copolymers via azide-alkyne cycloaddition chemistry. (c) 2016 Society of Chemical Industry | - |
dc.description.uri | 1 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-BLACKWELL | - |
dc.subject | azide | - |
dc.subject | post-polymerization modification | - |
dc.subject | polypropylene | - |
dc.subject | hypervalent iodine | - |
dc.subject | cycloaddition chemistry | - |
dc.title | Direct azidation of isotactic polypropylene and synthesis of "grafted to' derivatives thereof using azide-alkyne cycloaddition chemistry | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000389315700009 | - |
dc.identifier.scopusid | 2-s2.0-84994113225 | - |
dc.identifier.rimsid | 58301 | - |
dc.date.tcdate | 2018-10-01 | - |
dc.contributor.affiliatedAuthor | Christopher W. Bielawski | - |
dc.identifier.doi | 10.1002/pi.5180 | - |
dc.identifier.bibliographicCitation | POLYMER INTERNATIONAL, v.66, no.1, pp.70 - 76 | - |
dc.citation.title | POLYMER INTERNATIONAL | - |
dc.citation.volume | 66 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 70 | - |
dc.citation.endPage | 76 | - |
dc.date.scptcdate | 2018-10-01 | - |
dc.description.wostc | 5 | - |
dc.description.scptc | 7 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | CARBON-CENTERED RADICALS | - |
dc.subject.keywordPlus | PENDANT STYRENE GROUPS | - |
dc.subject.keywordPlus | HALO-ALPHA-ALKENES | - |
dc.subject.keywordPlus | CLICK CHEMISTRY | - |
dc.subject.keywordPlus | CATIONIC-POLYMERIZATION | - |
dc.subject.keywordPlus | STABLE AZIDOIODINANES | - |
dc.subject.keywordPlus | ROOM-TEMPERATURE | - |
dc.subject.keywordPlus | MATERIAL SCIENCE | - |
dc.subject.keywordPlus | SODIUM-AZIDE | - |
dc.subject.keywordPlus | ENOL ETHERS | - |
dc.subject.keywordAuthor | azide | - |
dc.subject.keywordAuthor | post-polymerization modification | - |
dc.subject.keywordAuthor | polypropylene | - |
dc.subject.keywordAuthor | hypervalent iodine | - |
dc.subject.keywordAuthor | cycloaddition chemistry | - |