Formation of a tetranickel octacarbonyl cluster from the CO2 reaction of a zero-valent nickel monocarbonyl species
DC Field | Value | Language |
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dc.contributor.author | Changho Yoo | - |
dc.contributor.author | Yunho Lee | - |
dc.date.available | 2017-01-20T08:32:06Z | - |
dc.date.created | 2016-07-18 | - |
dc.date.issued | 2016-06 | - |
dc.identifier.issn | 2052-1553 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/3293 | - |
dc.description.abstract | The reaction of a zerovalent nickel complex {Na}{(PNP)Ni(CO)} (1) with CO2(g) results in the formation of a tetrameric cluster complex {(PNCOONaP)Ni(CO)2}4 (2) as the major product along with {(PNP)Ni}2-μ-CO3-κ2O,O (3), {(PNP)Ni}2-μ-CO2-κ2C,O (4) and (PNP)Ni(CO) (5). A labelling experiment with 13CO2(g) reveals that not only the carbamate moeity but also the CO ligand in 2 originate from CO2(g). The formation of both a carbonyl species 2 and a carbonate species 3 indicates that nickel-mediated reductive disproportionation of CO2 occurs. Alternatively, a direct CO2 oxidative reaction of 1 occurs to produce {(PNP)Ni}2-μ-CO2-κ2C,O (4) in a minor pathway. The synthesis and characterization of 2 and other products are described herein. © 2016 the Partner Organisations | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Formation of a tetranickel octacarbonyl cluster from the CO2 reaction of a zero-valent nickel monocarbonyl species | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000378516300011 | - |
dc.identifier.scopusid | 2-s2.0-84974658539 | - |
dc.identifier.rimsid | 56143 | - |
dc.date.tcdate | 2018-10-01 | - |
dc.contributor.affiliatedAuthor | Changho Yoo | - |
dc.contributor.affiliatedAuthor | Yunho Lee | - |
dc.identifier.doi | 10.1039/c6qi00011h | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY FRONTIERS, v.3, no.6, pp.849 - 855 | - |
dc.relation.isPartOf | INORGANIC CHEMISTRY FRONTIERS | - |
dc.citation.title | INORGANIC CHEMISTRY FRONTIERS | - |
dc.citation.volume | 3 | - |
dc.citation.number | 6 | - |
dc.citation.startPage | 849 | - |
dc.citation.endPage | 855 | - |
dc.date.scptcdate | 2018-10-01 | - |
dc.description.wostc | 6 | - |
dc.description.scptc | 6 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |