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Rh(III)- and Ir(III)-catalyzed direct C-H bond transformations to carbon-heteroatom bonds Highly Cited Paper

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Title
Rh(III)- and Ir(III)-catalyzed direct C-H bond transformations to carbon-heteroatom bonds
Author(s)
Jeung Gon Kim; Kwangmin Shin; Sukbok Chang
Publication Date
2016-01
Journal
TOPICS IN ORGANOMETALLIC CHEMISTRY, v.55, no., pp.29 - 52
Publisher
SPRINGER-VERLAG BERLIN
Abstract
The direct manipulation of C-H bonds is now a powerful tool in chemical synthesis. In achieving the current high standard of research progresses, Rh(III) and Ir(III) complexes played an important role to understand the nature of C-H bond activation. While numerous stoichiometric reactions of hydrocarbons with Rh (III) or Ir(III) complexes were scrutinized, their use in catalytic transformations has been relatively undeveloped until recently. Given their outstanding reactivity in C-H activation, they are highly promising candidates for inducing mild C-H functionalizations. In spite of a short development history, numerous contributions from leading research groups made big strides in highly efficient and selective C-H bond transformations for the C-C and C-heteroatom bond formation. In this report, we specifically focus on the Rh(III)- or Ir(III)-mediated direct C-H functionalizations for the C-heteroatom bond formation that is now a rapidly growing area. This report presents the current status of such catalytic systems including scope of substrates and coupling partners as well as brief mechanistic descriptions. © Springer International Publishing Switzerland 2015
URI
https://pr.ibs.re.kr/handle/8788114/2659
ISSN
1436-6002
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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