BROWSE

Related Scientist

Researcher

Christopher W Bielawski
다차원 탄소재료 연구단
more info

Controlled Synthesis of an Alternating Donor-Acceptor Conjugated Polymer via Kumada Catalyst-Transfer Polycondensation

DC Field Value Language
dc.contributor.authorTodd, A.D.-
dc.contributor.authorChristopher W. Bielawski-
dc.date.available2016-01-25T00:12:12Z-
dc.date.created2015-12-07-
dc.date.issued2015-11-
dc.identifier.issn2161-1653-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/2271-
dc.description.abstractKumada catalyst-transfer polycondensation was used to synthesize poly(5,6-difluorobenzotriazole-alt-4-hexylthiophene) (PFBTzHT), an alternating donor-acceptor conjugated polymer, in a controlled manner. Through a series of kinetic studies, a linear relationship between the monomer conversion and the molecular weight of the resulting polymer was observed while maintaining narrow polydispersities (Ds ≤ 1.4). Moreover, the Mn displayed a linear relationship with the initial monomer-to-catalyst feed ratio, and polymers with Mns up to 25 kDa were successfully synthesized. All-conjugated block copolymers containing segments of PFBTzHT and poly(3-hexylthiophene) (P3HT) were also obtained in various compositions (30-70% P3HT) via sequential monomer addition in a single vessel. © 2015 American Chemical Society-
dc.languageENG-
dc.publisherAMER CHEMICAL SOC-
dc.titleControlled Synthesis of an Alternating Donor-Acceptor Conjugated Polymer via Kumada Catalyst-Transfer Polycondensation-
dc.typeArticle-
dc.type.rimsA-
dc.identifier.wosid000365147000014-
dc.identifier.scopusid2-s2.0-84947219361-
dc.description.wostc17-
dc.date.tcdate2018-10-01-
dc.date.scptcdate2018-10-01-
dc.contributor.affiliatedAuthorChristopher W. Bielawski-
dc.identifier.bibliographicCitationACS MACRO LETTERS, v.4, no.11, pp.1254 - 1258-
dc.description.scptc18-
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
Files in This Item:
4. acsmacrolett.pdfDownload

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse