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Cobalt(III)-catalyzed C-H amidation of arenes using acetoxycarbamates as convenient amino sources under mild conditions

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Title
Cobalt(III)-catalyzed C-H amidation of arenes using acetoxycarbamates as convenient amino sources under mild conditions
Author(s)
Pitambar Patel; Sukbok Chang
Subject
cobalt catalysis, C−H amidation, acetoxycarbamates, 6-arylpurines, arylamines
Publication Date
2015-02
Journal
ACS CATALYSIS, v.5, no.2, pp.853 - 858
Publisher
AMER CHEMICAL SOC
Abstract
The Co(III)-catalyzed direct C−H amidation of arenes has been developed using O-acylcarbamates as a convenient amino source. This reaction proceeded in high efficiency under external oxidant-free conditions with a broad range of arene substrates, including 6-arylpurines bearing sensitive functional groups, thus furnishing synthetically versatile arene N-carbamate products.
URI
https://pr.ibs.re.kr/handle/8788114/2116
DOI
10.1021/cs501860b
ISSN
2155-5435
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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