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A tin-free route to trans -Diels-Alder motifs by visible light photoredox catalysis

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Title
A tin-free route to trans -Diels-Alder motifs by visible light photoredox catalysis
Author(s)
Jun Hee Lee; Mho S.-I.
Publication Date
2015-03
Journal
JOURNAL OF ORGANIC CHEMISTRY, v.80, no.6, pp.3309 - 3314
Publisher
AMER CHEMICAL SOC
Abstract
A tin-free trans-Diels-Alder paradigm for the stereoselective synthesis of trans-fused polycyclic systems was developed through the photocatalytic reductive dehalogenation of α-haloketones promoted by visible light. Good to excellent diastereoselectivities were observed in the stereoselective construction of trans-fused octalone derivatives under mild reaction conditions. © 2015 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/2111
ISSN
0022-3263
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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