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Synthesis, Crystal Structure, and Magnetism in Fluoride Sulfates, A2VF3(SO4) (A = K, Rb, Cs)

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dc.contributor.authorJin, Yanling-
dc.contributor.authorSuheon Lee-
dc.contributor.authorZhang, Xinan-
dc.contributor.authorChen, Dan-
dc.contributor.authorZhu, Wenxuan-
dc.contributor.authorLi, Yaping-
dc.contributor.authorHuang, Qingqing-
dc.contributor.authorMun, Eundeok-
dc.contributor.authorChoi, Kwang-Yong-
dc.contributor.authorLü, Minfeng-
dc.date.accessioned2024-06-10T06:30:02Z-
dc.date.available2024-06-10T06:30:02Z-
dc.date.created2024-06-03-
dc.date.issued2024-06-
dc.identifier.issn1528-7483-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/15233-
dc.description.abstractThree novel alkali metal vanadium(III) fluoride sulfates, A2VF3(SO4) (A = K, Rb, Cs), were prepared through hydrothermal redox reactions. The products were isostructural with previously reported K2MnF3(SeO4) and featured one-dimensional chains of trans-VF4O2 octahedra that were connected by μ2-bridging oxygen atoms with SO4 units. In the title compounds, spin chains of V3+ (S = 1) with trans V-F-V bridges were arranged in a two-dimensional rectangular lattice. DC magnetization showed unpredictable ferromagnetic-like ordering at ∼0.6 K, accompanied by a weak hysteresis curve. At high temperatures, the dominant magnetic interactions were found to be antiferromagnetic, as deduced from the negative values of the Curie-Weiss temperature. © 2024 American Chemical Society.-
dc.language영어-
dc.publisherAmerican Chemical Society-
dc.titleSynthesis, Crystal Structure, and Magnetism in Fluoride Sulfates, A2VF3(SO4) (A = K, Rb, Cs)-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid001234448600001-
dc.identifier.scopusid2-s2.0-85194420476-
dc.identifier.rimsid83155-
dc.contributor.affiliatedAuthorSuheon Lee-
dc.identifier.doi10.1021/acs.cgd.4c00089-
dc.identifier.bibliographicCitationCrystal Growth & Design, v.24, no.11, pp.4428 - 4436-
dc.relation.isPartOfCrystal Growth & Design-
dc.citation.titleCrystal Growth & Design-
dc.citation.volume24-
dc.citation.number11-
dc.citation.startPage4428-
dc.citation.endPage4436-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalWebOfScienceCategoryCrystallography-
dc.relation.journalWebOfScienceCategoryMaterials Science, Multidisciplinary-
dc.subject.keywordPlusSERIES-
dc.subject.keywordPlusCO-
dc.subject.keywordPlusJAROSITE-
Appears in Collections:
Center for Artificial Low Dimensional Electronic Systems(원자제어 저차원 전자계 연구단) > 1. Journal Papers (저널논문)
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