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Daniel, HEDMAN
다차원 탄소재료 연구단
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Enhanced Mechanical, Thermal and Electrical Properties of High-Entropy HfMoNbTaTiVWZr Thin Film Metallic Glass and its Nitrides

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Title
Enhanced Mechanical, Thermal and Electrical Properties of High-Entropy HfMoNbTaTiVWZr Thin Film Metallic Glass and its Nitrides
Author(s)
Alvi, Sajid; Milczarek, Michal; Jarzabek, Dariusz M.; Daniel Hedman; Kohan, Mojtaba Gilzad; Levintant-Zayonts, Neonila; Vomiero, Alberto; Akhtar, Farid
Publication Date
2022-09
Journal
ADVANCED ENGINEERING MATERIALS, v.24, no.9
Publisher
WILEY-V C H VERLAG GMBH
Abstract
The inception of high-entropy alloy promises to push the boundaries for new alloy design with unprecedented properties. This work reports entropy stabilisation of an octonary refractory, HfMoNbTaTiVWZr, high-entropy thin film metallic glass, and derived nitride films. The thin film metallic glass exhibited exceptional ductility of approximate to 60% strain without fracture and compression strength of 3 GPa in micro-compression, due to the presence of high density and strength of bonds. The thin film metallic glass shows thermal stability up to 750 degrees C and resistance to Ar-ion irradiation. Nitriding during film deposition of HfMoNbTaTiVWZr thin film of strong nitride forming refractory elements results in deposition of nanocrystalline nitride films with compressive strength, hardness, and thermal stability of up to 10 GPa, 18.7 GPa, and 950 degrees C, respectively. The high amount of lattice distortion in the nitride films leads to its insulating behaviour with electrical conductivity as low as 200 S cm(-1) in the as-deposited film. The design and exceptional properties of the thin film metallic glass and derived nitride films may open up new avenues of development of bulk metallic glasses and the application of refractory-based high entropy thin films in structural and functional applications.
URI
https://pr.ibs.re.kr/handle/8788114/12862
DOI
10.1002/adem.202101626
ISSN
1438-1656
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
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