BROWSE

Related Scientist

cchf's photo.

cchf
분자활성촉매반응연구단
more info

ITEM VIEW & DOWNLOAD

Ditelluride, Terminal Tellurido, and Bis(tellurido) Motifs of Titanium

DC Field Value Language
dc.contributor.authorZatsepin, Pavel-
dc.contributor.authorJun-Hyeong Kim-
dc.contributor.authorGau, Michael R.-
dc.contributor.authorCarroll, Patrick J.-
dc.contributor.authorBimal Pudasaini-
dc.contributor.authorMu-Hyun Baik-
dc.contributor.authorMindiola, Daniel J.-
dc.date.accessioned2023-01-26T02:49:52Z-
dc.date.available2023-01-26T02:49:52Z-
dc.date.created2022-10-29-
dc.date.issued2022-07-
dc.identifier.issn0002-7863-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/12782-
dc.description.abstractHighly modular and rational syntheses of titanium compounds containing ditelluride, terminal telluride, and bis(telluride) structural motifs are disclosed in this study. Titanate anions bearing two cis and terminal telluride functionalities bound to the same metal center represent a unique example of a group 4 transition metal bis(chalcogenide) ion and are accessed in a simple, single-step procedure from Ti(III) bis(alkyl) complexes in the presence of an outer-sphere reductant and at least 3 equiv of Te0 powder. These compounds have been characterized crystallographically and spectroscopically with some preliminary reactivity reported for the anionic Ti(═Te)2 motif. We also report solution 125Te NMR spectral data in addition to theoretical studies addressing the bonding and structure for these titanate bis(tellurido) systems.-
dc.language영어-
dc.publisherNLM (Medline)-
dc.titleDitelluride, Terminal Tellurido, and Bis(tellurido) Motifs of Titanium-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000894293500001-
dc.identifier.scopusid2-s2.0-85135382787-
dc.identifier.rimsid79079-
dc.contributor.affiliatedAuthorJun-Hyeong Kim-
dc.contributor.affiliatedAuthorBimal Pudasaini-
dc.contributor.affiliatedAuthorMu-Hyun Baik-
dc.identifier.doi10.1021/jacs.2c05558-
dc.identifier.bibliographicCitationJournal of the American Chemical Society, v.144, no.29, pp.13066 - 13070-
dc.relation.isPartOfJournal of the American Chemical Society-
dc.citation.titleJournal of the American Chemical Society-
dc.citation.volume144-
dc.citation.number29-
dc.citation.startPage13066-
dc.citation.endPage13070-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusSE-
dc.subject.keywordPlusSELENIDO-
dc.subject.keywordPlusSULFIDO-
dc.subject.keywordPlusCHALCOGENIDES-
dc.subject.keywordPlusREACTIVITY-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusZIRCONIUM-
dc.subject.keywordPlusVANADIUM-
dc.subject.keywordPlusLIGANDS-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
There are no files associated with this item.

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse