C4-Selective C-H Borylation of Pyridinium Derivatives Driven by Electron Donor-Acceptor Complexes
DC Field | Value | Language |
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dc.contributor.author | Wonjun Choi | - |
dc.contributor.author | Minseok Kim | - |
dc.contributor.author | Kangjae Lee | - |
dc.contributor.author | Seongjin Park | - |
dc.contributor.author | Sungwoo Hong | - |
dc.date.accessioned | 2023-01-26T02:22:16Z | - |
dc.date.available | 2023-01-26T02:22:16Z | - |
dc.date.created | 2023-01-02 | - |
dc.date.issued | 2022-12 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/12478 | - |
dc.description.abstract | © 2022 American Chemical Society.The photoinduced C4-selective C-H borylation of pyridines was achieved using electron donor-acceptor complexes derived from a Lewis base and N-amidopyridinium salts under external oxidant- and photocatalyst-free conditions. Notably, the nucleophilic character of phosphite-ligated boryl radicals enables addition of a radical to position C4 of pyridinium salts to afford C4-borylated heteroarenes that are otherwise difficult to obtain. This approach provides a versatile platform for the installation of both phosphite- and amine-coordinated boron groups on a series of pyridines under mild conditions, demonstrating excellent C4-positional selectivity for the pyridine scaffolds. | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | C4-Selective C-H Borylation of Pyridinium Derivatives Driven by Electron Donor-Acceptor Complexes | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000901584800001 | - |
dc.identifier.scopusid | 2-s2.0-85144426594 | - |
dc.identifier.rimsid | 79599 | - |
dc.contributor.affiliatedAuthor | Wonjun Choi | - |
dc.contributor.affiliatedAuthor | Minseok Kim | - |
dc.contributor.affiliatedAuthor | Kangjae Lee | - |
dc.contributor.affiliatedAuthor | Seongjin Park | - |
dc.contributor.affiliatedAuthor | Sungwoo Hong | - |
dc.identifier.doi | 10.1021/acs.orglett.2c03882 | - |
dc.identifier.bibliographicCitation | Organic Letters, v.24, no.51, pp.9452 - 9457 | - |
dc.relation.isPartOf | Organic Letters | - |
dc.citation.title | Organic Letters | - |
dc.citation.volume | 24 | - |
dc.citation.number | 51 | - |
dc.citation.startPage | 9452 | - |
dc.citation.endPage | 9457 | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | LIGHT | - |
dc.subject.keywordPlus | RADICALS | - |
dc.subject.keywordPlus | SCOPE | - |