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Conjugated organic framework with three-dimensionally ordered stable structure and delocalized π clouds

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dc.contributor.authorJia Guo-
dc.contributor.authorYanhong Xu-
dc.contributor.authorShangbin Jin-
dc.contributor.authorLong Chen-
dc.contributor.authorToshihiko Kaji-
dc.contributor.authorYoshihito Honsho-
dc.contributor.authorMatthew A. Addicoat-
dc.contributor.authorJangbae Kim-
dc.contributor.authorAkinori Saeki-
dc.contributor.authorHyot Cherl Ihee-
dc.contributor.authorShu Seki-
dc.contributor.authorStephan Irle-
dc.contributor.authorMasahiro Hiramoto-
dc.contributor.authorJia Gao-
dc.contributor.authorDonglin Jiang-
dc.date.available2015-04-20T06:36:36Z-
dc.date.created2014-08-11ko
dc.date.issued2013-11-
dc.identifier.issn2041-1723-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/1220-
dc.description.abstractCovalent organic frameworks are a class of crystalline organic porous materials that can utilize p–p-stacking interactions as a driving force for the crystallization of polygonal sheets to form layered frameworks and ordered pores. However, typical examples are chemically unstable and lack intrasheet p-conjugation, thereby significantly limiting their applications. Here we report a chemically stable, electronically conjugated organic framework with topologically designed wire frameworks and open nanochannels, in which the p conjugation-spans the two-dimensional sheets. Our framework permits inborn periodic ordering of conjugated chains in all three dimensions and exhibits a striking combination of properties: chemical stability, extended p-delocalization, ability to host guest molecules and hole mobility. We show that the p-conjugated organic framework is useful for high on-off ratio photoswitches and photovoltaic cells. Therefore, this strategy may constitute a step towards realizing ordered semiconducting porous materials for innovations based on two-dimensionally extended p systems.-
dc.description.uri1-
dc.language영어-
dc.publisherNATURE PUBLISHING GROUP-
dc.titleConjugated organic framework with three-dimensionally ordered stable structure and delocalized π clouds-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000328023000007-
dc.identifier.scopusid2-s2.0-84887732334-
dc.identifier.rimsid493ko
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorHyot Cherl Ihee-
dc.identifier.doi10.1038/ncomms3736-
dc.identifier.bibliographicCitationNATURE COMMUNICATIONS, v.4, pp.2736-
dc.citation.titleNATURE COMMUNICATIONS-
dc.citation.volume4-
dc.citation.startPage2736-
dc.date.scptcdate2018-10-01-
dc.description.wostc152-
dc.description.scptc161-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > 1. Journal Papers (저널논문)
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J.Guo_D.Jiang_NatureComm._2013_Conjugatedorganicframeworkwiththree-dimensionallyordered~.pdfDownload

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