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분자활성촉매반응연구단
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Photoinduced α-C−H Amination of Cyclic Amine Scaffolds Enabled by Polar-Radical Relay

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dc.contributor.authorWongyu Lee-
dc.contributor.authorDongwook Kim-
dc.contributor.authorSangwon Seo-
dc.contributor.authorSukbok Chang-
dc.date.accessioned2022-07-28T04:41:53Z-
dc.date.available2022-07-28T04:41:53Z-
dc.date.created2022-05-10-
dc.date.issued2022-06-
dc.identifier.issn1433-7851-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/11923-
dc.description.abstract© 2022 Wiley-VCH GmbH.Herein, we report a polar-radical relay strategy for α-C−H amination of cyclic amines with N-chloro-N-sodio-carbamates. The relay is initiated by in situ generation of cyclic iminium intermediate using N-iodosuccinimide (NIS) oxidant as an initiator, which then operates through a series of polar (addition and elimination) and radical (homolysis, hydrogen- and halogen atom transfer) reactions to enable the challenging C−N bond formation in a controlled manner. A broad range of α-amino cyclic amines were readily accessed with excellent regioselectivity, and the superb applicability was further demonstrated by functionalization of biologically relevant compounds.-
dc.language영어-
dc.publisherJohn Wiley and Sons Inc-
dc.titlePhotoinduced α-C−H Amination of Cyclic Amine Scaffolds Enabled by Polar-Radical Relay-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000786629400001-
dc.identifier.scopusid2-s2.0-85128607542-
dc.identifier.rimsid78130-
dc.contributor.affiliatedAuthorWongyu Lee-
dc.contributor.affiliatedAuthorDongwook Kim-
dc.contributor.affiliatedAuthorSangwon Seo-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1002/anie.202202971-
dc.identifier.bibliographicCitationAngewandte Chemie - International Edition, v.61, no.25-
dc.relation.isPartOfAngewandte Chemie - International Edition-
dc.citation.titleAngewandte Chemie - International Edition-
dc.citation.volume61-
dc.citation.number25-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusN BOND FORMATION-
dc.subject.keywordPlusHYPERVALENT IODINE(III)-
dc.subject.keywordPlusNITROGEN-HETEROCYCLES-
dc.subject.keywordPlusC(SP(3))-H AMINATION-
dc.subject.keywordPlusNITRENE TRANSFER-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusAMIDATION-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusRING-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordAuthorAmination-
dc.subject.keywordAuthorAmines-
dc.subject.keywordAuthorRadicals-
dc.subject.keywordAuthorReaction Mechanisms-
dc.subject.keywordAuthorSustainability-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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