BROWSE

Related Scientist

cchf's photo.

cchf
분자활성촉매반응연구단
more info

ITEM VIEW & DOWNLOAD

Installing a molecular truss beam stabilizes MOF structures

DC Field Value Language
dc.contributor.authorHong Ki Kim-
dc.contributor.authorJung, Jong-Yeong-
dc.contributor.authorGyumin Kang-
dc.contributor.authorMu-Hyun Baik-
dc.contributor.authorChoi, Eun-Young-
dc.date.accessioned2022-06-08T01:51:02Z-
dc.date.available2022-06-08T01:51:02Z-
dc.date.created2022-06-02-
dc.date.issued2022-05-
dc.identifier.issn2057-3960-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/11693-
dc.description.abstractEnhancing the stability and durability of metal-organic frameworks (MOFs) is vital for practical applications because many promising MOF materials suffer from phase transitions and/or structural decompositions with humidity being a particularly damaging condition. In mechanical engineering, the frame of buildings and furniture can be stabilized significantly by installing a truss beam. Employing the same principle, we functionalized the organic component of MOF-5 to contain a carbazole moiety that can act as a molecular truss beam by reaching across the corner and forming a stable pi-pi interaction with a phenyl group on the edge position of the MOF-skeleton. This structural support enhanced the stability of the MOF substantially, allowing the designed MOF to maintain compositional integrity under steam conditions at 90 degrees C for similar to 5 days. The unmodified MOF-5 shows clear signs of structural collapse after similar to 1 h.-
dc.language영어-
dc.publisherNATURE PORTFOLIO-
dc.titleInstalling a molecular truss beam stabilizes MOF structures-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000799812600001-
dc.identifier.scopusid2-s2.0-85130734684-
dc.identifier.rimsid78245-
dc.contributor.affiliatedAuthorHong Ki Kim-
dc.contributor.affiliatedAuthorGyumin Kang-
dc.contributor.affiliatedAuthorMu-Hyun Baik-
dc.identifier.doi10.1038/s41524-022-00799-3-
dc.identifier.bibliographicCitationNPJ COMPUTATIONAL MATERIALS, v.8, no.1-
dc.relation.isPartOfNPJ COMPUTATIONAL MATERIALS-
dc.citation.titleNPJ COMPUTATIONAL MATERIALS-
dc.citation.volume8-
dc.citation.number1-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaMaterials Science-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalWebOfScienceCategoryMaterials Science, Multidisciplinary-
dc.subject.keywordPlusMETAL-ORGANIC FRAMEWORKS-
dc.subject.keywordPlusEFFECTIVE CORE POTENTIALS-
dc.subject.keywordPlusPOROUS COORDINATION POLYMERS-
dc.subject.keywordPlusCARBON-DIOXIDE-
dc.subject.keywordPlusHYDROGEN STORAGE-
dc.subject.keywordPlusWATER STABILITY-
dc.subject.keywordPlusBASIS-SETS-
dc.subject.keywordPlusADSORPTION-
dc.subject.keywordPlusRESISTANT-
dc.subject.keywordPlusSELECTIVITY-
dc.subject.keywordAuthorMETAL-ORGANIC FRAMEWORKS-
dc.subject.keywordAuthorEFFECTIVE CORE POTENTIALS-
dc.subject.keywordAuthorPOROUS COORDINATION POLYMERS-
dc.subject.keywordAuthorCARBON-DIOXIDE-
dc.subject.keywordAuthorHYDROGEN STORAGE-
dc.subject.keywordAuthorWATER STABILITY-
dc.subject.keywordAuthorBASIS-SETS-
dc.subject.keywordAuthorADSORPTION-
dc.subject.keywordAuthorRESISTANT-
dc.subject.keywordAuthorSELECTIVITY-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
There are no files associated with this item.

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse