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Gold carbene complexes and beyond: new avenues in gold(I)-carbon coordination chemistry

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Title
Gold carbene complexes and beyond: new avenues in gold(I)-carbon coordination chemistry
Author(s)
Florian F. Mulks
Publication Date
2022-04
Journal
GOLD BULLETIN, v.55, no.1, pp.1 - 13
Publisher
SPRINGER HEIDELBERG
Abstract
The different coordination modes in carbon-gold(I) complexes are spotlighted with a focus on gold(I). The emergence of gold carbene complexes and their critical discussion in the community is presented, and an overview of their bonding fundamentals and synthetic procedures is given. Several intriguing and sometimes highly reactive gold-carbon coordination complexes that were recently synthesised and isolated are reviewed and a critical outlook into their potential applications is provided. This includes vinylidene and higher cumulenylidene complexes, free carbenes with gold substituents, carbodicarbene complexes, and non-Fischer/Schrock sesquicarbene complexes.
URI
https://pr.ibs.re.kr/handle/8788114/11232
DOI
10.1007/s13404-021-00298-1
ISSN
2364-821X
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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