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KIM, Youyoung
분자활성 촉매반응 연구단
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Ir(iii)-Catalysed electrooxidative intramolecular dehydrogenative C-H/N-H coupling for the synthesis of N-H indoles

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Title
Ir(iii)-Catalysed electrooxidative intramolecular dehydrogenative C-H/N-H coupling for the synthesis of N-H indoles
Author(s)
Youyoung Kim; Dongwook Kim; Sukbok Chang
Publication Date
2021-11-19
Journal
CHEMICAL COMMUNICATIONS, v.57, no.92, pp.12309 - 12312
Publisher
ROYAL SOC CHEMISTRY
Abstract
Herein, an iridium(iii)-catalysed electrooxidative intramolecular dehydrogenative C-H/N-H coupling of unprotected 2-alkenyl anilines is described. The developed method allows the synthesis of a variety of 3-substituted N-H indole scaffolds under undivided electrolytic conditions. Mechanistic studies suggest that the reaction proceeds through the electro-oxidation induced reductive elimination pathway.
URI
https://pr.ibs.re.kr/handle/8788114/10747
DOI
10.1039/d1cc05882g
ISSN
1359-7345
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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