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나노물질및화학반응연구단
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Random-graft polymer-directed synthesis of inorganic mesostructures with ultrathin frameworks

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dc.contributor.authorChangbum Jo-
dc.contributor.authorYongbeom Seo-
dc.contributor.authorKanghee Cho-
dc.contributor.authorJaeheon Kim-
dc.contributor.authorHye Sun Shin-
dc.contributor.authorMunhee Lee-
dc.contributor.authorJeong-Chul Kim-
dc.contributor.authorSang Ouk Kim-
dc.contributor.authorJeong Yong Lee-
dc.contributor.authorHyotCherl Ihee-
dc.contributor.authorRyong Ryoo-
dc.date.available2015-04-20T05:55:11Z-
dc.date.created2014-08-11-
dc.date.issued2014-05-
dc.identifier.issn1433-7851-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/1028-
dc.description.abstractA widely employed route for synthesizing mesostructured materials is the use of surfactant micelles or amphiphilic block copolymers as structure-directing agents. A versatile synthesis method is described for mesostructured materials composed of ultrathin inorganic frameworks using amorphous linear-chain polymers functionalized with a random distribution of side groups that can participate in inorganic crystallization. Tight binding of the side groups with inorganic species enforces strain in the polymer backbones, limiting the crystallization to the ultrathin micellar scale. This method is demonstrated for a variety of materials, such as hierarchically nanoporous zeolites, their aluminophosphate analogue, TiO2 nanosheets of sub-nanometer thickness, and mesoporous TiO2, SnO2, and ZrO2. This polymer-directed synthesis is expected to widen our accessibility to unexplored mesostructured materials in a simple and mass-producible manner. In the right direction: Mesostructured inorganic materials, such as zeolite nanosponge, TiO2 nanosheets, and nanosponges of TiO2, SnO2, and ZrO2 were synthesized using amorphous polymers as the structure-directing agent. Many of these materials possessed quite uniform mesopores. Some of them even exhibited small-angle X-ray diffraction. The structure-directing mechanism is also presented. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.description.uri1-
dc.language영어-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectAmorphous materials-
dc.subjectMesoporous materials-
dc.subjectNanosheets-
dc.subjectTitanium dioxide-
dc.subjectX ray diffraction-
dc.subjectZirconium alloys-
dc.subjectAmphiphilic block copolymers-
dc.subjectMesostructured materials-
dc.subjectMesostructures-
dc.subjectnanosponges-
dc.subjectRandom distribution-
dc.subjectSmall angle x-ray diffractions-
dc.subjectStructure directing agents-
dc.subjectSurfactant micelles-
dc.subjectPolymers-
dc.titleRandom-graft polymer-directed synthesis of inorganic mesostructures with ultrathin frameworks-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000335476400020-
dc.identifier.scopusid2-s2.0-84900014103-
dc.identifier.rimsid541ko
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorChangbum Jo-
dc.contributor.affiliatedAuthorYongbeom Seo-
dc.contributor.affiliatedAuthorKanghee Cho-
dc.contributor.affiliatedAuthorJaeheon Kim-
dc.contributor.affiliatedAuthorHye Sun Shin-
dc.contributor.affiliatedAuthorMunhee Lee-
dc.contributor.affiliatedAuthorJeong-Chul Kim-
dc.contributor.affiliatedAuthorSang Ouk Kim-
dc.contributor.affiliatedAuthorJeong Yong Lee-
dc.contributor.affiliatedAuthorHyotCherl Ihee-
dc.contributor.affiliatedAuthorRyong Ryoo-
dc.identifier.doi10.1002/anie.201310748-
dc.identifier.bibliographicCitationANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.53, no.20, pp.5117 - 5121-
dc.citation.titleANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.citation.volume53-
dc.citation.number20-
dc.citation.startPage5117-
dc.citation.endPage5121-
dc.date.scptcdate2018-10-01-
dc.description.wostc24-
dc.description.scptc24-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordAuthormesostructures-
dc.subject.keywordAuthornanosheets-
dc.subject.keywordAuthornanosponges-
dc.subject.keywordAuthorpolymers-
dc.subject.keywordAuthorstructure directing agents-
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > 1. Journal Papers (저널논문)
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