Highly Stable, Water-Dispersible Metal-Nanoparticle-Decorated Polymer Nanocapsules and Their Catalytic Applications

Abstract

A facile synthesis of highly stable, water-dispersible metal-nanoparticle- decorated polymer nanocapsules (M@CB-PNs: M=Pd, Au, and Pt) was achieved by a simple two-step process employing a polymer nanocapsule (CB-PN) made of cucurbit[6]uril (CB[6]) and metal salts. The CB-PN serves as a versatile platform where various metal nanoparticles with a controlled size can be introduced on the surface and stabilized to prepare new water-dispersible nanostructures useful for many applications. The Pd nanoparticles on CB-PN exhibit high stability and dispersibility in water as well as excellent catalytic activity and recyclability in carbon-carbon and carbon-nitrogen bond-forming reactions in aqueous medium suggesting potential applications as a green catalyst. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.