Tandem synthesis of amides and secondary amines from esters with primary amines under solvent-free conditions
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jeongbin Lee | - |
dc.contributor.author | Muthaiah S. | - |
dc.contributor.author | Soon Hyeok Hong | - |
dc.date.available | 2015-04-20T05:40:46Z | - |
dc.date.created | 2014-08-11 | - |
dc.date.issued | 2014-08 | - |
dc.identifier.issn | 1615-4150 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/961 | - |
dc.description.abstract | An iridium(III)-catalyzed tandem synthesis of amides and amines from esters under solvent-free conditions is described. A commercially available iridium(III) complex, [Cp*IrCl2]2, with sodium acetate showed the best activity for the synthesis of amides and secondary amines. The amide was formed by ester-amide exchange which generates an alcohol in situ which is subsequently transformed to a secondary amine via hydrogen autotransfer. This synthetic protocol with high atom economy generates water as the sole by-product and can afford amides and amines from various esters in a one-pot reaction, expanding the synthetic versatility of ester transformations. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | - |
dc.description.uri | 1 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | amides | - |
dc.subject | amines | - |
dc.subject | esters | - |
dc.subject | hydrogen transfer | - |
dc.subject | iridium | - |
dc.title | Tandem synthesis of amides and secondary amines from esters with primary amines under solvent-free conditions | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000340567100030 | - |
dc.identifier.scopusid | 2-s2.0-84906214859 | - |
dc.identifier.rimsid | 337 | ko |
dc.date.tcdate | 2018-10-01 | - |
dc.contributor.affiliatedAuthor | Jeongbin Lee | - |
dc.contributor.affiliatedAuthor | Soon Hyeok Hong | - |
dc.identifier.doi | 10.1002/adsc.201400319 | - |
dc.identifier.bibliographicCitation | ADVANCED SYNTHESIS & CATALYSIS, v.356, no.11-12, pp.2653 - 2660 | - |
dc.citation.title | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.citation.volume | 356 | - |
dc.citation.number | 11-12 | - |
dc.citation.startPage | 2653 | - |
dc.citation.endPage | 2660 | - |
dc.date.scptcdate | 2018-10-01 | - |
dc.description.wostc | 15 | - |
dc.description.scptc | 16 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | amides | - |
dc.subject.keywordAuthor | amines | - |
dc.subject.keywordAuthor | esters | - |
dc.subject.keywordAuthor | hydrogen transfer | - |
dc.subject.keywordAuthor | iridium | - |